Benzyl Acrylate
Benzyl acrylate (C6H5CH2OCOCH=CH2) is a commercially important aromatic ester of acrylic acid used in adhesives, coatings, and reactive diluents for UV-curing systems. Classified under HTS 2916.12.10.00 due to its aromatic benzyl group and unsaturated acrylic acid backbone. The double bond enables free-radical polymerization.
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Alternative Classifications
This product could be classified differently depending on its characteristics or intended use.
If benzyl alcohol content exceeds 20% as impurity or co-product
Mixtures dominated by alcohol component shift to Chapter 29 alcohols heading.
If pre-polymerized to low molecular weight oligomer
Partially polymerized acrylic materials classified as acrylic polymers in Chapter 39.
If derived from other unsaturated acyclic acids (not acrylic)
Esters of other unsaturated acids like methacrylic or crotonic fall in different 2916.39 subheading.
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Import Tips & Compliance
• Include polymerization inhibitor specification (typically MEHQ or hydroquinone) as it affects stability declarations
• Aromatic acrylates are UN3077 Environmentally Hazardous Substances—ensure proper IMDG/ADR shipping papers
Related Products under HTS 2916.12.10.00
Phenylmethyl Acrylate
Phenylmethyl acrylate is an aromatic ester of acrylic acid featuring a phenyl group attached to the methyl ester moiety. It falls under HTS 2916.12.10.00 as an aromatic unsaturated acyclic monocarboxylic acid ester with the characteristic double bond from acrylic acid. Used primarily in specialty polymer synthesis and UV-curable coatings.
2-Phenoxyethyl Acrylate
2-Phenoxyethyl acrylate contains both phenyl ether and acrylic functionalities, making it ideal for flexible coatings and optical films. Its classification under HTS 2916.12.10.00 reflects the dominant acrylic acid ester structure with aromatic substitution via the phenoxy group. Provides low volatility and good adhesion properties.
2-Phenylpropyl Acrylate
2-Phenylpropyl acrylate features a chiral center and aromatic substitution, used in chiral polymer synthesis and pharmaceutical intermediates. HTS 2916.12.10.00 classification based on acrylic acid ester with aromatic acyclic chain. Racemic mixtures most common commercially.
N-Phenylglycidyl Acrylate
N-Phenylglycidyl acrylate combines acrylic ester, epoxide, and aniline functionalities for advanced crosslinking resins. Aromatic character from phenyl group justifies HTS 2916.12.10.00 classification as primary acrylic acid ester. Used in high-performance composites and electronics.
4-Phenylbutyl Acrylate
4-Phenylbutyl acrylate provides hydrophobic aromatic character for water-resistant coatings and pressure-sensitive adhesives. The extended alkyl chain with terminal phenyl qualifies as aromatic acrylic ester under HTS 2916.12.10.00. Low Tg enables soft, tacky polymers.
Cumyl Acrylate
Cumyl acrylate (1-methyl-1-phenylethyl acrylate) features sterically hindered alpha-methylbenzyl group for specialty impact modifiers. Aromatic substitution pattern clearly fits HTS 2916.12.10.00 as acrylic acid ester. Provides high Tg polymers with good clarity.