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Phosphorus Pentachloride 99% Pure Crystals

Phosphorus pentachloride (PCl5) in crystalline form with 99% purity, used primarily as a chlorinating agent in organic synthesis to convert carboxylic acids to acid chlorides. It falls under HTS 2812.14.00.00 as a chloride oxide of the nonmetal phosphorus, specifically phosphorus pentachloride, meeting the chemical definition in Chapter 28. Typically packaged in sealed glass bottles to prevent hydrolysis by moisture.

Import Duty Rates by Country of Origin

Origin CountryMFN RateCh.99 SurchargesTotal Effective Rate
🇨🇳ChinaFree+35.0%35%
🇲🇽MexicoFree+10.0%10%
🇨🇦CanadaFree+10.0%10%
🇩🇪GermanyFree+10.0%10%
🇯🇵JapanFree+10.0%10%

Alternative Classifications

This product could be classified differently depending on its characteristics or intended use.

2828.90.00.00Higher: 38.7% vs 35%

If containing >70% phosphorus and used as hypophosphite precursor

Hypophosphorous acid derivatives or phosphorus-containing chlorides with specific compositions fall under phosphides or other halides in 2828.

2812Same rate: 35%

If classified as phosphorus trichloride (PCl3) variant

Lower chloride forms like PCl3 are separately provided for in the preceding subheading 2812.10.

3824.99Lower: 15% vs 35%

If mixed with organic solvents or stabilizers for retail sale

Chemical preparations or mixtures not chemically defined pure compounds go to mixtures heading 3824.

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Import Tips & Compliance

Classify strictly as chemically defined PCl5; impurities over certain thresholds may shift to 2828 or 2829

Mandatory DOT/UN 1806 hazardous material declaration and proper packaging for corrosive solids

Verify REACH/CLP compliance for EU origins; obtain TSCA certification for US registration